Geometric switching of linear to area negative thermal expansion in uniaxial metal–organic frameworks

The origin of uniaxial negative thermal expansion in layered perovskites

Exceptional negative thermal expansion in isoreticular metal-organic frameworks.

The thermal-expansion properties of substances are very important in materials design; for example, cracks form when joined materials expand or contract by different amounts upon heating. The most famous example of a substance that contracts when heated is ice: it transforms into water, which has a higher density than ice. Negative thermal expansion (NTE) in solids is relatively rare, although ...

Local Structural Distortion Induced Uniaxial Negative Thermal Expansion in Nanosized Semimetal Bismuth

The corrugated layer structure bismuth has been successfully tailored into negative thermal expansion along c axis by size effect. Pair distribution function and extended X-ray absorption fine structure are combined to reveal the local structural distortion for nanosized bismuth. The comprehensive method to identify the local structure of nanomaterials can benefit the regulating and controlling...

Uniaxial Negative Thermal Expansion and Mechanical Properties of a Zinc-Formate Framework

The thermal expansion behavior of a metal-formate framework, Zn(HCOO)₂·2(H₂O) (1), has been systematically studied via variable temperature single-crystal X-ray diffraction. Our results demonstrate that this formate exhibits significant negative thermal expansion (NTE, -26(2) MK-1) along its c-axis. Detailed structural analyses reveal that the large NTE response is attributed to the 'hinge-stru...

Negative Thermal Expansion

Introduction Many materials which we encounter in everyday life expand on heating. This fact of life is easily highlighted with a simple experiment that we are all familiar with and involves a metallic sphere passing through a metal ring. At room temperature, the sphere is of such a size that it can easily pass through the ring, but after the sphere is heated, it will have expanded with the res...